What is a pre-emergent herbicide?
A pre-emergent herbicide prevents weeds from gaining a foothold. A post emergent herbicide i.e. sulfonylureas kills weeds when they are already present. The key to using pre-emergents is knowing how they work and behave in the soil. Failing to do this this will lead to poor results.
In the above image, ryegrass is being affected by the pre-emergent diflufenican which is still active in the soil. Our recent turf blog covers split applications of pre-emergents and reasons for pre-emergent failure.
How do pre-emergent herbicides work?
Pre-emergents have zero effect on weed seeds. They act by preventing germinated weed seedlings from becoming established by forming a barrier at the soil surface. The majority of pre-emergents act on weed roots. In contrast, oxadiazon is the only shoot active pre-emergent for use in turf and this is the active in Echelon® and Echelon Duo®.
To work properly you must wash the herbicide into the soil. It must also be present when the weed seeds are germinating so soil moisture is vital to allow these to work.
Are pre emergents safe?
Table showing the modes of action of turf registered pre emergents.
Chemical Group | Active constituent (common trade name) | LD 50 Oral |
3 | ||
Inhibition of microtubule assembly | ||
Benzamides | propyzamide (Proforce Checkpoint®*500SC) | 5,620 |
Benzoic acids | chlorthal-dimethyl (Chlorthal-dimethyl 900®) | >10,000 |
Dinitroanilines: (DNAs) | pendimethalin (Proforce Battalia®) | 1,250 |
prodiamine (Barricade® herbicide) | >5,000 | |
Pyridines | dithiopyr (Dimension®) | >5,000 |
12 | ||
Inhibition of carotenoid biosynthesis at the phytoene desaturase step (PDS inhibitors) | ||
Phenyl-ethers | diflufenican (Warhead Trio®*) | >2,000 |
14 | ||
Inhibition of protoporphyrinogen oxidase (PPO inhibitors) | ||
N-Phenyl-oxadiazolones | oxadiazon (Echelon®, Oxafert®) | >5,000 |
15 | ||
Inhibition of very long chain fatty acid synthesis (VLCFA inhibitors) | ||
α-Chloroacetamides | dimethenamid (Freehand®*) | 849 |
S-metalochlor (Pennmag®) | 2,780 | |
Benzofurans | ethofumesate (Tramat®) | >20,000 |
29 | ||
Inhibition of cellulose biosynthesis | ||
Alkylazines | indaziflam (Specticle®) | >2,000 |
When not to use pre-emergent herbicides.
- Firstly, its solubility;
- Second, how well it binds to soil particles;
- Third, the weather conditions when it is applied, and finally
- The application rate.
It is also important to know the weed history of a site as this helps in choosing the right pre-emergent to use. There is little point in using a pre-emergent if it doesn’t work against the target weed.
The following is a summary of these factors. After all, always remember that pre-emergents don’t all behave the same!
Factors affecting the successful use of pre-emergent herbicides:
Volatilization.
Table showing the vapour pressure of common pre-emergents.
s-metolachlor (Pennmag) | 3.7 | Actives with a vapour pressure of greater than 1mPa are generally considered volatile. |
pendimethalin (Battalia) | 3.34 | |
dimethenamid-P (Freehand) | 2.5 | |
oxadiazon (Ronstar/Echelon) | 0.67 | |
terbuthylazine (Numchuk Quad) | 0.152 | Actives with a vapour pressure of less than 1mPa are generally considered non-volatile |
propyzamide (Rustler) | 0.058 | |
Prodiamine (Barricade/Onset 10GR) | 0.0033 | |
diflufenican (Warhead) | 4.25 x 10-3 | |
Indaziflam (Specticle) | 2.5 X 10-05 | |
Oryzalin (Prolan) | 1.1 X 10-07 |
The persistence of pre-emergent herbicides.
Table showing the Average DT50* values for common pre-emergents.
DT50 Value | ||
dimethenamid-P (Freehand) | 7 | |
s-metolachlor (Pennmag) | 21 | |
terbuthylazine (Numchuk Quad) | 22 | 0 to 30 Non persistent |
dithiopyr (Dimension) | 39 | |
Oryzalin (Prolan) | 44.8 | 30 to 100 Moderately persistent |
propyzamide (Rustler) | 60 |
|
pendimethalin (Battalia) | 100 | |
diflufenican (Warhead) | 105 | |
prodiamine (Dimension/Onset 10GR) | 120 | >100 Persistent |
indaziflam (Specticle) | 150 | |
oxadiazon (Ronstar/Echelon) | 502 | Very persistent |
Not Watering in the Product.
Table showing the solubility of pre-emergent turf herbicides.
diflufenican (Warhead) | 0.05 | |
Prodiamine (Barricade/Onset 10GR) | 0.013 | |
pendimethalin (Battalia) | 0.33 | |
oxadiazon (Ronstar/Echelon) | 0.57 | |
Oryzalin (Prolan) | 1.13 | |
Dithiopyr (Dimension) | 1.38 | Low solubility (0 to 49mg/L @ 20C). Likely to require moist conditions for incorporation and uptake. |
Indaziflam (Specticle) | 2.8 | |
terbuthylazine (Numchuk Quad) | 7 | |
propyzamide (Rustler) | 9 | |
s-metolachlor (Pennmag) | 480 | High solubility (> 501mg/L @ 20C). |
dimethenamid-P (Freehand) | 1499 |
Soil properties.
-
High sand content soils have little ability to hold onto any chemicals;
-
In low organic matter soils less herbicide is likely to become “tied up”;
-
Physical movement occurs on slopes and areas of thin turf cover where water movement occurs.
The sorption coefficient (Koc) is a measure of how much a chemical binds to soils. Chemicals that have a high Koc tend to bind tightly to soil and organic matter i.e. pendimethalin. Low Koc herbicides i.e. metalochlor are less likley to bind to clay or high organic matter soils and are likely to be mobile.
So if we rank from those least likely to bind to those with the highest binding: Metalochlor < Dithiopyr < Oxadiazon < Pendimethalin = Prodiamine.
Table showing the average adsorption coefficients for common pre-emergent turf herbicides.
pendimethalin (Battalia) | 17491 | Koc > 4000 | Likely to bind tightly to soil and organic matter |
Prodiamine (Barricade/Onset 10GR) | 12710 | Non-mobile. | |
oxadiazon (Ronstar/Echelon) | 3200 |
| |
diflufenican (Warhead) | 1622 | ||
indaziflam (Specticle) | 1000 | Koc 500 to 4000 slightly mobile |
|
oryzalin (Prolan) | 949 |
| |
propyzamide (Checkpoint) | 840 | ||
dithiopyr (Dimension) | 801 |
| |
terbuthylazine (Numchuk Quad) | 230 | Koc 75 to 500 moderately mobile |
|
dimethenamid-P (Freehand) | 218 | ||
s-metolachlor (Pennmag) | 200 | Koc 15 to 75 Mobile |
Chemical Breakdown of pre-emergent herbicides.
- Firstly, soil temperatures. The higher the soil temperature the faster the breakdown;
- Secondly, soil moisture. In moist soils this is quicker than in dry soils;
- Thirdly, adequate soil oxygen and nutrients will speed up this decay, and finally
- A neutral soil pH.
Herbicide | Soil Texture and Organic Matter | Soil pH | Soil moisture and Temperature |
Dimethenamid-p (Freehand®) |
|
Not a factor | Soluble and may leach in sandy soils after intense rainfall |
S-metalochlor (Pennmag®) |
|
Not a factor | Soluble, but less soluble than Dimethenamid-p and so has a lower activity |
Incorrect pre-emergent herbicide timing.
Poor timing has a major impact on any results and in my opinion this is the main reason for product failures. So, lets clear something up. If you can see weeds, most of the time its going to be a waste of money applying a pre-emergent.
The table below shows critical soil temperatures for common grass weeds (measured at 10cm depth) courtesy of North Carolina State University.
Weed | Temperature °C |
winter grass/ annual bluegrass | 21 |
Crowsfoot | 16-18 |
Summergrass | 12-15 |
Knotweed | 2-10 |
Because crowsfoot germinates at a higher temperature than summergrass it tends to germinate 2-8 weeks later in the spring and knotweed germinates even earlier. This means that if you are planning make a pre emergent application for crowsfoot a smart move is to make this around 2 weeks after you see summergrass.
Photodegradation
This is the breakdown of chemicals due to the action of sunlight at the soil surface. Yellow coloured herbicides like prodiamine and pendimethalin, can all decay in sunlight if you do not water them in after application.
Getting the best results:
The following are some general tips to give you a better chance of getting great results:
Make sure your equipment is properly calibrated.
Correct calibration is important if you use a granular or liquid as failing to do this means it will be applied unevenly and you’ll get poor results.
Choosing pre-emergents on price.
Buying something purely on price never guarantees good results. Instead, you should select the right product for your situation. There are five factors to consider:
- Firstly what weeds are you trying to control? Different products work better on different weeds and the cheapest option might not even work on your target weed;
- Secondly what is the true cost of application? You should consider factors such as rate, length of control and bag size;
- Thirdly what is your turf type? Not all of these are safe on all turf types. There isn’t much point in buying the cheapest product on the market if its going to kill your turf;
- Next when you make a purchase are you buying it from a supplier who can give you good agronomic advice on how to get the best results?
- Lastly how long do you want it to last? Longer control isn’t always the best if your example you want to seed later etc.
If the actives are the same, look at how easy is it to apply and handle. For instance, both Barricade® herbicide and Onset 10GR® contain the same active but one is a liquid and the other a granule. In the next section there are pros and cons to both of these.
Are Granular or liquid applications best?
- First, for larger areas liquids are easier to apply;
- Second liquids are less likely to wash away in a storm or heavy rainfall and
- Third, liquids move into the soil a lot quicker.
Influence of granule size on summergrass control 6 months after treating with pre-emergent herbicides. (Kelly and Coats, 1999)
Granule size number/ gram | Oxadiazon | Prodiamine |
23 | 58 | 43 |
58 | 67 | 71 |
165 | 72 | 74 |
465 | 72 | 81 |
1,310 | 70 | 82 |
3,728 | 66 | 83 |
10,606 | 68 | 83 |
LSD (0.05) | 7 | 7 |
Successful use of pre-emergent herbicides; Generic vs branded?
A generic product performs as well as other registered products and if you don’t believe me look at the labels for generic and branded products.
Isomers.
Your left and right hands are isomers as they are the same but one is the mirror image of the other. During the manufacture of metalochlor it creates a blend of four isomers. These all have the same chemical formula but have a different molecular make up.
Pennmag® contains 88% of the S and 12% of the R isomers; Meteor® contains roughly equal amounts of the S and R isomers. Research shows that a higher amount of the S isomer works better. This doesn’t mean that the R isomer doesn’t work but it may not work as well. In fact both the R and combination of R and S formulations have around 50% less activity. Interestingly, on the launch of S metolachlor in the USA, the application rate was 30% less than other metalochlor products.
Timing their use for spring applications
Microbial activity is at its lowest in the spring due to low cool soil temperatures that exist. This means that ideally applying pre-emergent herbicides earlier than you would generally think will still give excellent results. The reason for this is due to the low level of microbial activity that breaks down these herbicides.
As discussed previously summergrass germinates when soil temperatures at a depth of 100mm are between 12-15°C whilst crowsfoot germinates later when soil temperatures are between 16-18°C. This means that in regions such as Canberra, the Southern Highlands and Melbourne that these can be applied in the autumn at the high rate and will provide season long control of summergrass the next year. This is especially the case if this is followed by a split-application in the spring.
Mixing pre and post emergent herbicides to delay resistance
A mix of both a pre and a post emergent works better than simply rotating chemistry for slowing down the development of resistance. This approach also:
- Has a larger application window which allows for changes in the timing of winter grass germination due to weather variations;
- Produces a better playing surface and turf quality than applying either alone;
- Increases application flexibility and allows for weather extremes such as :
- Heavy rainfall that can leach and breakdown herbicides;
Delay weed resistance by changing the chemistry
To avoid the development of herbicide weed resistance you should rotate with products with different modes of action every third or fourth year.
Mixing pre and post emergent herbicides to delay resistance
A mix of both a pre and a post emergent works better than simply rotating chemistry for slowing down the development of resistance. This approach also:
- Has a larger application window which allows for changes in the timing of winter grass germination due to weather variations;
- Produces a better playing surface and turf quality than applying either alone;
- Increases application flexibility and allows for weather extremes such as :
- Heavy rainfall that can leach and breakdown herbicides;
Using pre-emergents safely.
Turf safety and seeding interval vary dependant on which pre emergent you use. If the chemical is still active in the soil, any seeding work will fail, so make sure that you carry out any seeding work after the time period listed on the label. This means you need to plan ahead and be aware of any future use.
Table showing pre-emergent safety on turf.
Turf type | s-metolachlor | dithiopyr | Oryzalin | propyzamide | pendimethalin | prodiamine | indaziflam | oxadiazon | dimethenamid-P (Freehand+) |
Couch | Safe to use+ | OK to use these | OK++ | Fine to use | |||||
QLD Blue couch | OK | OK | No | OK to use these | |||||
Buffalo | OK | OK | No | OK to use these | |||||
Bentgrass | Safe to use+ | Not safe to use | OK | Not safe to use | |||||
Ryegrass | OK | OK | No | No | OK | Not safe to use | |||
Tall fescue | OK | OK | No | No | Not safe to use | ||||
Zoysia | OK | OK | No | No | OK to uses these | ||||
Kikuyu | OK to use these | ||||||||
Reseeding period | Established | 3-6 months | 18 weeks | 60 days | 30-60 days | 6 months | 12 months | 4-5 months | 3 months |
Irrigation volume | At least 3mm | Not required | 10-15mm | 25mm | 10-15mm within 1 day | 6mm within 7 days | 3-6mm within 21 days | Irrigate within 2 days. | 10-15mm |
Root pruning | Yes these all prune roots | No | Yes | ||||||
safe to use+ | Not golf greens | ||||||||
++ | Not santa anna |
Root pruning
Many pre-emergents have negative effects on root growth which is called “root pruning”. Good examples of these are Barricade® and Specticle®. So if your turf is under stressor it already has a poor root system avoid the use of these as they will only send your turf backwards.
The amount of root pruning that occurs is a direct result of the particular chemical and the turf type.
2018 work into how pre-emergents affect roots on couch grass establishment.
- Specticle® did not achieve a 50% couch cover by the end of the trial;
- Only Ronstar® did not increase the number of days required to reach 50% cover;
- All treatments reduced root mass 6 weeks after treatment (WAT);
- By 10 WAT, Barricade®, pendimethalin, and Specticle® had less root mass;
- At 4 WAT, all treatments other than Ronstar® had shorter roots;
- 10 WAT, only Dimension®, S-metolachlor, and Specticle® had shorter roots;
- The conclusion was that Specticle®, Dimension®, and S-metolachlor are not safe on newly established hybrid couchgrass and should be avoided during establishment.
FAQ
What pre emergent herbicide kills bindi?
Before you go putting down a pre emergent herbicide realise that the best way of stopping any weed is to have healthy dense turf. If you have this it will choke out competing weeds and so you don’t have to spray any chemicals. However in some cases you might need to apply a pre emergent herbicide.
My two go to pre emergents for bindii are an oxadiazon based product such as Echelon® or Echelon Duo® or for longer control products based on prodiamine such as Onset 10GR® if I want to use a granular option or Barricade® herbicide if I want to use a liquid. Both of these active ingredients give excellent control against this troublesome weed.
How does pre emergent herbicide work?
Withouit going into too much detail pre emergent herbicdies form a barrier a the surface and prevent weeds from establishing. They have no effect at all on weed seeds.
Does pre emergent herbicide kill grass?
If you follow the label the answer is a simply no.
Where to buy pre emergent herbicide near me?
Gilba solutions supplies into NSW, VIC, QLD and the ACT. For areas outside of these feel free to contact us and we are only too happy to point you in the right direction as to where to get product at the best price.
Are there any new pre emergent herbicides?
The newest pre emergent active ingredient is indaziflam sold as Specticle® which was introduced several years ago. However, the newest products on the market are both granular products and produced by Indigo Specialty. These are called Echelon Duo® and Onset 10GR® These are based on oxadiazon and prodiamine respectively.
Can I core after applying a pre-emergent herbicide?
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After an applying oxadiazon, core aeration did not affect crowsfoot control.
-
Monroe et. al., also showed that aeration did not affect the control of summer grass2Monroe, J. H., W. M. Lewis. J. M. DiPaola. 1990. Aerification effects on preemergence herbicide activity. Weed Science Society of America Abstracts 30:27.
References
After Graduating from Newcastle University with an Hons Degree in Soil Science in 1988, Jerry then worked for the Sports Turf Research Institute (STRI) before emigrating to Australia in 1993.
He followed this by gaining a Grad Dip in Business Managment from UTS and has worked in a number of managment roles for companies as diverse as Samsung Australia, Arthur Yates and Paton Fertilizers.
He has always had a strong affinity with the Australian sports turf industry and as a result he established Gilba Solutions in 1993. Jerry has written over 100 articles and two books on a wide range of topics such as Turf Pesticides and Nutrition which have been published in Australia and overseas.